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影响γ-Al2O3负载纳米级SO42-/TiO2固体超强酸催化活性的因素的研究
Study on the Effect on Catalytic Activity of γ-Al2O3 Supported Nano-sized SO42-/TiO2 Solid Super Acid
【摘要】 考察了焙烧温度、硫酸浓度对自制的γ-Al2O3负载纳米级SO42-/TiO2固体超强酸的酸强度、比表面积的影响;用不同条件下制得的γ-Al2O3负载纳米级SO42-/TiO2固体超强酸催化乙酸和正丁醇酯化反应,检测乙酸转化率;讨论了影响γ-Al2O3负载纳米级SO42-/TiO2固体超强酸催化活性的因素,为批量制备提供参考.
【Abstract】 Theγ-Al2O3 supported nano-sized SO42-/TiO2 solid super acid was prepared.The effect of sulphuric acid concentration and calcining temperature on acidity and specific surface area of theγ-Al2O3 supported nano-sized SO42-/TiO2 solid super acid was studied.The effect on catalytic activity of theγ-Al2O3 supported nano-sized SO42-/TiO2 for esterification of acetic and n-butanol was discussed,which can provide the reference for mass production.
【关键词】 γ-Al2O3负载纳米级SO42-/TiO2;
固体超强酸;
催化活性;
【Key words】 γ-Al2O3 supported SO42-/TiO2; solid super acid; catalytic activity;
【Key words】 γ-Al2O3 supported SO42-/TiO2; solid super acid; catalytic activity;
【基金】 河北建筑工程学院科研基金项目(ZD201408)
- 【文献出处】 河北建筑工程学院学报 ,Journal of Hebei Institute of Architecture and Civil Engineering , 编辑部邮箱 ,2017年04期
- 【分类号】O643.36
- 【下载频次】68