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Thermal-stable mixed-cation lead halide perovskite solar cells

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【作者】 顾帅朱鹏臣林仁兴唐明瑶祝世宁朱嘉

【Author】 Shuai Gu;Pengchen Zhu;Renxing Lin;Mingyao Tang;Shining Zhu;Jia Zhu;National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences and School of Physics, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University;

【机构】 National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences and School of Physics, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University

【摘要】 As perovskite solar cells show tremendous potential for widespread applications, we find that adding inorganic thermal-stable cesium ions into MAPbI3 results in significantly improves thermal stability. For un-encapsulated perovskite devices, the energy conversion efficiency maintains about 75% of its original value(over 15%) in the MA0.85Cs0.05PbI3 device under 80 min of heating at 140°C in a dry atmosphere(RH ≤ 30%). With significantly improved thermal stability achieved by a convenient process, it is expected that this type of mixed-cation perovskites can further facilitate large scale applications.

【Abstract】 As perovskite solar cells show tremendous potential for widespread applications, we find that adding inorganic thermal-stable cesium ions into MAPbI3 results in significantly improves thermal stability. For un-encapsulated perovskite devices, the energy conversion efficiency maintains about 75% of its original value(over 15%) in the MA0.85Cs0.05PbI3 device under 80 min of heating at 140°C in a dry atmosphere(RH ≤ 30%). With significantly improved thermal stability achieved by a convenient process, it is expected that this type of mixed-cation perovskites can further facilitate large scale applications.

【基金】 jointly supported by the State Key Program for Basic Research of China (No. 2015CB659300);the National Natural Science Foundation of China (Nos. 11621091 and 11574143);the Natural Science Foundation of Jiangsu Province (Nos. BK20150056);the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD);the Fundamental Research Funds for the Central Universities
  • 【文献出处】 Chinese Optics Letters ,中国光学快报(英文版) , 编辑部邮箱 ,2017年09期
  • 【分类号】TM914.4
  • 【被引频次】2
  • 【下载频次】39
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