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丁腈橡胶复合材料的制备与性能

Preparation and Properties of Nitrile Rubber Composite

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【作者】 陈永军邹华伍社毛张立群

【Author】 CHEN Yongjun;ZOU Hua;WU Shemao;ZHANG Liqun;Engineering Technology Center of Advanced Elastomer Material,Beijing University of Chemical Technology;Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials,Beijing University of Chemical Technology;

【机构】 北京化工大学北京市先进弹性体工程技术研究中心北京化工大学北京市新型高分子材料制备与加工重点实验室

【摘要】 通过物理共混法制备出各组分分散均匀的丁腈橡胶复合材料,研究了硫化剂、防老剂、耐寒增塑剂的种类及用量对丁腈橡胶复合材料性能的影响。结果表明:当防老剂体系为4010NA/RD/AW/NBC/石蜡,用量分别为1,1,1.5,2,1质量份时,丁腈橡胶复合材料具有优异的耐热空气和耐臭氧老化性能;当耐寒增塑剂为DOA且其用量为6质量份时,丁腈橡胶复合材料具有良好的耐低温和耐油老化性能;采用复合硫化体系DCP/S/DM/CZ且用量分别为2.5,0.5,0.3,0.5质量份时,丁腈橡胶复合材料的耐热空气老化和耐低温性能较好;当NBR(35%)/NBR(26%)、ZnO、SA、N550、S、DM、CZ、DCP、DOA、4010NA、RD、NBC、AW、石蜡的加入量分别为50/50,5,1.5,60,0.5,0.3,0.5,2.5,6,1.5,1,1,1.5,1质量份时,丁腈橡胶复合材料具有优异的综合性能。

【Abstract】 The nitrile rubber composites with component dispersed uniformly was prepared by physical blending method.The effect of vulcanizing agent,antioxidant and cold-resistant plasticizer on the properties of nitrile rubber composite was studied.The results show that when the antioxidant system was 4010NA/RD/AW/NBC/paraffin and dosages were 1,1,1.5,2,1phr,respectively,nitrile rubber composite had excellent hot air and ozone aging resistance.When the cold-resistant plasticizer was DOA and its dosage was 6phr,nitrile rubber composite had excellent low temperature resistance and good oil resistance.When the compound vulcanization system DCP/S/DM/CZ was used and dosages were 2.5,0.5,0.3,0.5phr,respectively,nitrile rubber composite had better hot air aging resistance and low temperature resistance.When the dosages of NBR(35%)/NBR(26%),ZnO,SA,N550,S,DM,CZ,DCP,DOA,4010 NA,RD,NBC,AW,paraffin were 50/50,5,1.5,60,0.5,0.3,0.5,2.5,6,1.5,1,1,1.5,1phr,nitrile rubber composites had the excellent comprehensive properties.

  • 【文献出处】 机械工程材料 ,Materials for Mechanical Engineering , 编辑部邮箱 ,2017年09期
  • 【分类号】TQ333.7
  • 【被引频次】9
  • 【下载频次】357
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