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生物活性炭降解低浓度邻苯二甲酸酯的挂膜研究

Biofilm Formation on Biological Activated Carbon for Degradation of Low-concentration PAEs

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【作者】 陈秋丽张朝升刘宏英荣宏伟张可方

【Author】 CHEN Qiu-li;ZHANG Chao-sheng;LIU Hong-ying;RONG Hong-wei;ZHANG Ke-fang;Key Laboratory for Water Quality Security and Protection in Pearl River Delta <Ministry of Education and Guangdong Province>,Guangzhou University;College of Urban Consturction,Zhongkai University of Agriculture and Engineering;

【机构】 广州大学省部共建教育部珠江三角洲水质安全与保护实验室仲恺农业工程学院城市建设学院

【摘要】 以DMP、DEP、DBP和DEHP为目标物质,开展了生物活性炭降解低浓度PAEs的挂膜研究。当进水PAEs浓度为10μg/L且采用人工投加营养物质的方式时,挂膜周期约为30 d;挂膜启动过程中,随着微生物数量和种群的不断增加,生物活性炭对CODMn、NH3-N和PAEs的去除效果逐渐变好;挂膜成功后,对CODMn、NH3-N的去除率均达到了60%以上,对DMP、DEP和DBP的去除率均维持在95%以上,对DEHP的去除率则稳定在80%左右。生物活性炭对PAEs起降解作用的主要是杆状菌和球状菌,活性炭和微生物的协同作用增强了生物活性炭降解PAEs的能力,尤其对低分子、短侧链的PAEs,生物活性炭的降解效果更好。

【Abstract】 Taking DMP,DEP,DBP and DEHP as the target substances,the experimental research on biofilm formation on the biological activated carbon for removing low-concentration phthalic acid esters(PAEs) was carried out.The results showed that the biofilm formation cycle was about 30 d with influent concentration of 10 μg/L for PAEs and artificial addition of nutrients.During biofilm formation,the removal efficiencies of CODMn,NH3-N and PAEs were increased with increase in microbial number and population.After the successful formation of biofilm,the removal rates of CODMn and NH3-N reached more than 60%,the removal rates of DMP,DEP and DBP were maintained above 95%,and the removal rate of DEHP was stable at around 80%.Bacilli and cocci in biological activated carbon process played a major role in the degradation of PAEs,and the synergy of activated carbon and microorganisms could enhance the degradation of PAEs,especially for low molecular/short side chain PAEs,their degradation effect was better.

【基金】 国家自然科学基金资助项目(21477027,51278133);广东省科技计划项目(2014A020216049);广州市教育系统创新团队项目(13C01);广东省高校创新人才项目(2014KQNCX105)
  • 【文献出处】 中国给水排水 ,China Water & Wastewater , 编辑部邮箱 ,2017年01期
  • 【分类号】TU991.2
  • 【被引频次】4
  • 【下载频次】174
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