【摘要】 烯烃及其衍生物异构化是一种利用碳碳双键沿骨架碳链发生位置迁移或顺反构型变换构建新烯烃的合成方法,对于有机合成、日用化学品合成、原料油应用和天然产物合成等均有着举足轻重的作用。本文综合论述了自1960年代以来烯烃及其衍生物异构化的五种催化体系的研究进展,重点结合笔者的研究工作,介绍光催化在有机化合物中碳碳双键异构反应中的应用及其发展趋势。更多还原

【Abstract】 C=C double bond isomerization(DBI)is a method for synthesizing new organic compounds from olefins and theirs derivatives,which was based on C=C migration along carbon chain and cis/trans transform,and it plays an important role in the fields of organic synthesis,synthesis of daily chemicals,raw oil’s development and synthesis of natural products and so on.In this paper,advances of five types of catalytic methods for DBI of olefins and its derivatives since 1960 swere discussed in detail;Based on his recent work,the author mainly introduces application and development of photo catalysis in DBI of olefins and theirs derivatives.更多还原