【摘要】 采用无氧Schlenk真空技术,在无水乙醇介质中,将水合三氯化钌与α-水芹烯加热回流,一步合成了对伞花烃二氯化钌（Ⅱ）二聚体（[Ru（p-cymene）Cl₂]₂）化合物,产率93.8%,用溶剂缓慢挥发法培养出单晶。元素分析、质谱（MS）、核磁共振(¹H-NMR、¹³C-NMR)和红外光谱（IR）等分析表明产物为目标化合物;X射线单晶衍射仪表征获得的晶体结构参数表明,该化合物为正交晶系、Fdd2空间群,[Ru（p-cymene）Cl₂]₂为二聚体化合物。更多还原

【Abstract】 [Ru（p-cymene）Cl₂]₂,an important molecular catalyst,was synthesized in one-step process from RuCl₃·3 H₂O in alcohol by adding α-phellandrene as the anion ligand.The yield was 93.8%.The structure of the target complex was confirmed by elemental analysis,MS,1 H-NMR,13 C-NMR,IR,and further determined by X-ray diffraction analysis after single crystals were cultured using the solvent evaporation.The results show the complex is in the triclinic system with a space group of Fdd2.has a dimmeric structural profile.更多还原