【摘要】 利用水热方法合成了一种Keggin型多酸基有机无机杂化材料,化学式为（Hpydz）Na[Co（pydz）₄（H₂O）₂][SiW₁₂O₄₀]·3H₂O（pydz=pyridazine）.单晶X-射线研究表明,在该化合物中,Keggin型多阴离子与钠离子连接构筑成三维孔状结构,其中钴-哒嗪阳离子有机基团作为客体分子,通过静电相互作用存在于三维孔道结构中,构筑成有机-无机杂化材料.该化合物属于单斜晶系,空间群为C₂/c,晶胞参数a=1.937 7（2）nm,b=1.678 8（2）nm,c=1.768 0（2）nm,α=90°,β=98.612（3）°,γ=90°,V=5.686 51nm³.更多还原

【Abstract】 A Keggin-type polyoxometalate-based organic-inorganic hybrid material（Hpydz）Na[Co（pydz）₄（H₂O）₂][SiW₁₂O₄₀]·3 H₂O was synthesized by hydrothermal method.Single crystal X-ray diffraction analysis reveals that the Keggin-type polyoxoanions were connected by sodium cations to form three dimensional porous structure.In this three dimensional porous structure,the [Co（Hpydz）₄（H₂O）₂]²⁺ cationic groups act the guest molecules,and the Keggin-type polyoxoanions surround them,resulting in the organic-inorganic hybrid materials.Title compound crystallizes in the monoclinic system,space group c₂/c with a=1.937 7（2）nm,b=1.678 8（2）nm,c=1.768 0（2）nm,α=90°,β=98.612（3）°,γ=90°,V=5.686 51 nm³.更多还原