【摘要】 利用离子热法合成了一种新颖的多金属氧酸盐超分子化合物Cu₄（Bbi）₄[SiW₁₂O₄₀]·H₂O.采用红外光谱、TGA光谱和单晶X射线衍射对该化合物进行了表征.结果表明,合成的化合物是一个具有很大空隙的一维梯形链,并由一维梯形链形成了三维超分子结构.电化学性质研究表明,该化合物可能是一种理想的电极材料.更多还原

【Abstract】 A novel polyoxometalates supramolecular compound was synthesized by the ionothermal synthesis Cu₄（Bbi）₄[SiW₁₂O₄₀]·H₂O.The structure of the compound is determined by the single crystal X-ray diffraction,and the results show that the compound is a one-dimensional trapezoidal chain with a large void,and the three-dimensional supramolecular structure is formed by a-dimensional trapezoid chains.In addition,the electrochemical properties of the compound is studied.更多还原