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Cu/Zn/Ce/ZSM-5分子筛的碱改性及催化性能研究

Study on Alkali Modification of Cu/Zn/Ce/ZSM-5 and Its Catalytic Performance

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【作者】 涂盛辉林立骆中璨刘婷杨昆忠杜军

【Author】 TU Shenghui;LIN Li;LUO Zhongcan;LIU Ting;YANG Kunzhong;DU Jun;Key Laboratory of Poyang Lake Environment and Resource Utilization of Ministry of Education,School of Resources,Environmental and Chemical Engineering,Nanchang University;

【机构】 南昌大学资源环境与化工学院鄱阳湖环境与资源利用教育部重点实验室

【摘要】 采用NaOH溶液和金属离子(Cu2+、Zn2+、Ce4+)改性ZSM-5分子筛。通过SEM、XRD等表征手段,探讨NaOH溶液浓度、Cu/Zn/Ce物质的量比以及不同制备方法对ZSM-5分子筛形貌及性能的影响。以光催化辅助降解酸性大红GR模拟废水,考察改性后的ZSM-5分子筛的催化活性。结果表明,当NaOH溶液的浓度为0.2mol/L、Cu负载量为8%、Cu/Zn/Ce物质的量比为8∶4∶1、制备方法为溶胶-凝胶法时,分子筛的催化性能最佳,离子溶出量较小。

【Abstract】 ZSM-5 zeolite was modified by NaOH solution and metal ion(Cu2+,Zn2+,Ce4+).The effects of NaOH solution concentration,Cu/Zn/Ce molar ratio and the different preparation methods on the morphology and properties of ZSM-5 zeolite were investigated by means of SEM and XRD.The catalytic activity of modified ZSM-5 zeolite was investigated by photocatalytic degradation of acid red GR simulated waste water.The results show that when the NaOH solution is 0.2 mol/L,the loading of Cu is8%,the ratio of Cu/Zn/Ce is 8∶4∶1,the preparation method is sol-gel method,the catalytic performance is the best and the ion dissolution is less.

【基金】 国家自然科学基金(51162022)
  • 【分类号】O643.36
  • 【被引频次】8
  • 【下载频次】343
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