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腰果酚聚氧乙烯醚的表面性能研究

Study on the surface performance of cardanol polyoxyethylene ether

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【作者】 赵雪华黄中瑞康文倩王利民车飞翟兆凯

【Author】 ZHAO Xue-hua;HUANG Zhong-rui;KANG Wen-qian;WANG Li-min;CHE Fei;ZHAI Zhao-kai;Shanghai Key Laboratory of Functional Materials Chemistry;Institute of Fine Chemicals,School of Chemistry and Molecular Engineering,East China University of Science and Technology;Shanghai Bronkow Chemical Co.,Ltd.;

【机构】 上海市功能性材料化学重点实验室华东理工大学化学与分子工程学院精细化工研究所上海邦高化学有限公司

【摘要】 研究了腰果酚聚氧乙烯醚BGF-10的表面活性及不同添加剂对其表面活性的影响。结果表明,在25℃时BGF-10的临界胶束浓度cmc=6.09×10-6mol/L,最低表面张力γcmc=38.08 m N/m,具有较好的抗硬水能力。BGF-10对一价的无机盐具有较强的抗盐性,随着二价无机盐浓度的增加,BGF-10的表面活性增强。一元醇能够降低BGF-10的表面张力,随着一元醇浓度的增加,BGF-10形成胶束的能力先升高后降低。BGF-10与表面活性剂复配具有一定的增效作用,尤其是与十六烷基三甲基溴化铵(CTAB)形成的复配体系,其cmc增效2.52%,γcmc增效11.49%。BGF-10对液体石蜡的乳化能力好,且具有增稠和低泡的性能。

【Abstract】 Surface activity of cardanol polyoxyethylene ether BGF-10 and the effects of different additives on the surface activity were studied. Results show that the critical micelle concentration( cmc) of BGF-10 is 6. 09 × 10-6mol/L,and the lowest surface tension( γcmc) is 38. 08 m N/m at 25 ℃. Moreover,BGF-10 displays a better resistance to hard water and a strong salt tolerance to monovalent inorganic salts. With the increase of concentration of divalent inorganic salt,the surface activity of BGF-10 is enhanced. Monohydric alcohol can reduce the surface tension of BGF-10. The ability of BGF-10 to form micelles increases in the beginning and then decreases with the increase of monohydric alcohol concentration. BGF-10 displays a synergistic effect with other surfactants,especially with hexadecyltrimethylammonium bromide( CTAB),and its cmc synergizes upto 2. 52%,while the γcmcsynergizes upto 11. 49%. BGF-10 displays a good emulsifying power for paraffin oil,as well as both thickening and defoaming performance.

【基金】 国家自然科学基金资助项目(21272069)
  • 【文献出处】 日用化学工业 ,China Surfactant Detergent & Cosmetics , 编辑部邮箱 ,2017年09期
  • 【分类号】TQ423
  • 【被引频次】6
  • 【下载频次】301
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