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新疆阜康矿区煤的吸附孔分形特征试验研究

The experimental study on the fractal characteristics of coal adsorbed pore in Fukang mining district of Xinjiang

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【作者】 林海飞程博曾强严敏张超

【Author】 Lin Haifei;Cheng Bo;Zeng Qiang;Yan Min;Zhang Chao;School of Safety Science & Engineering,Xi’an University of Science & Technology;Xinjiang Coal Research Institute;

【机构】 西安科技大学安全科学与工程学院新疆维吾尔自治区煤炭科学研究所

【摘要】 为研究新疆阜康矿区煤的吸附孔分形特征,进行了低温氮吸附试验,采用BET模型和BJ H模型计算得到煤的孔隙比表面积及体积,应用FHH模型计算煤的孔隙分形维数,分析了分形维数与煤质参数及孔隙参数关系。试验结果表明:阜康矿区煤的孔隙A=D一3在研究尺度范围内分形特征明显,分形维数为2.25045~2.56277;煤的孔隙分形维数与水分呈负相关关系,与灰分呈正相关关系,与固定碳含量呈二次函数关系,与挥发分关系不明显;分形维数与孔隙直径为负相关关系,与孔隙比表面积、孔隙体积呈正相关关系;分形维数与中孔比表面积及体积占比呈负相关关系,与微孔和过渡孔体积占比呈正相关性,但与两者比表面积占比无明显关系。

【Abstract】 to study the fractal characteristics of coal adsorbed pore in Fukang mining district of Xinjiang,the experiments of adsorbed with nitrogen at low temperature were carried out,the coal pore specific surface area and volume were calculated by employing the BET and BJH model,the coal pore fractal dimension was calculated by adopting the FHH model,the relationships of fractal dimension and the parameters of coal quality and pore were analyzed.The experimental results show that the fractal characteristics of coal pore of Fukang mining district are very obvious within the scope of study,the fractal dimension is 2.25045 to 2.56277;the fractal dimension of coal pore is negatively correlated with moisture content and positively correlated with ash content,it exhibits an impact of quadratic relationship on the fixed carbon content,the relationship of fractal dimension and volatile matter is not obvious;the fractal dimension of coal pore is negatively correlated with pore diameter and positively correlated with pore specific surface area and volume;the fractal dimension of coal pore is negatively correlated with the mescopore ratios in pore specific surface area and volume and positively correlated with micropore and transition pore ratios in pore volume,however,the relationship of fractal dimension and micropore and transition pore ratios in pore specific surface area is not obvious.

【基金】 国家自然科学基金项目(51327007,51174157);陕西省自然科学青年科技新星专项(2014KJXX69);新疆维吾尔自治区科技支撑基金资助项目(201333110)
  • 【分类号】TD712.1
  • 【被引频次】6
  • 【下载频次】154
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