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pH值对Q235钢在模拟土壤中腐蚀行为的影响

Effect of p H Value on Corrosion Behavior of Q235 Steel in an Artificial Soil

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【作者】 黄涛陈小平王向东米丰毅刘芮李向阳

【Author】 HUANG Tao;CHEN Xiaoping;WANG Xiangdong;MI Fengyi;LIU Rui;LI Xiangyang;Division of Engineering Steel,Central Iron and Steel Research Institute;School of Material Science and Engineering, Kunming University of Science and Technology;

【机构】 钢铁研究总院工程用钢研究所昆明理工大学材料科学与工程学院

【摘要】 采用一种新型的土壤腐蚀评价方法——硅藻土模拟土壤实验室加速腐蚀法,进行了Q235钢在不同p H值模拟土壤腐蚀介质中的埋片20 d的腐蚀实验。结果表明:随着模拟土壤的p H值从4.5升高至8.5,Q235钢的腐蚀速率持续下降,这一规律与已有的实际土壤下的腐蚀规律相同,而试样表面由较严重的全面腐蚀转变为轻微的局部腐蚀;酸性模拟土壤条件与碱性条件下的腐蚀产物组成一致,主要是α-Fe OOH,Fe3O4,γ-Fe OOH和Fe2O3,但α-Fe OOH和Fe3O4含量差别大,碱性条件下腐蚀产物中Fe3O4的含量上升,α-Fe OOH的含量下降。

【Abstract】 Coupons of the grounding material Q235 steel were buried in an artificial soil of diatomite with different p H values for 20 d, and then the corrosion behavior of the steel was examined.The results indicated that the p H value of the artificial soil had a great effect on the corrosion behavior of Q235 steel. With the increasing of p H value, the corrosion rate of the steel in the artificial soil decreased, which accorded fairly well with that in the actual soil, correspondingly the corrosion type of the coupons turned from rather serious uniform corrosion to slight local corrosion. The corrosion products formed in acidic artificial soil are consistent with those in an alkaline artificial soil, they all composed mainly of α-Fe OOH, Fe3O4, γ-Fe OOH and Fe2O3, however the products in the late case contained higher Fe3O4 and less α-Fe OOH.

【关键词】 土壤腐蚀模拟土壤Q235钢pH值
【Key words】 soil corrosionartificial soilQ235 steelpH value
【基金】 陕西电力科学研究院项目(2012037)资助
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society for Corrosion and Protection , 编辑部邮箱 ,2016年01期
  • 【分类号】TG172.4
  • 【被引频次】25
  • 【下载频次】550
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