【摘要】 合成了具非线性光学性能的杂环偶氮生色团的单体化合物甲基丙烯酸(4-苯并噻唑-2-偶氮基苯基)酯(BAMA),并通过自由基聚合得到均聚物聚甲基丙烯酸(4-苯并噻唑-2-偶氮基苯基)酯(PBAMA).利用1 H-NMR验证了聚合物的结构,采用Z-扫描法研究了聚合物溶液的三阶非线性光学性能.结果表明,单体和聚合物均具有较高的三阶非线性光学系数.更多还原

【Abstract】 The azoheterocycle compound 4-benzothiazole-2-ylazo-phenyl-methacrylate(BAMA)containing vinyl is designed as monomer.The polymer containing azoheterocycle nonlinearity optical property(NLO)chromophore in each side chain is synthesized via free radical polymerization.The structure of the polymers is characterized by 1 H-NMR.The third-order NLO coefficient of the polymer is measured by Z-scan technique.Obvious third-order nonlinear optical property is observed for the monomer and the polymer.更多还原