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凝固点降低法测定摩尔质量实验体系的绿色化研究

Green chemical research on experimental system of determining molecular weight by freezing point fall method

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【作者】 孟庆民俞英黄海燕张民杨娣红高成地

【Author】 MENG Qing-min;YU Ying;HUANG Hai -yan;ZHANG Min;YANG Di -hong;GAO Cheng-di;College of Science,China University of Petroleum;

【机构】 中国石油大学(北京)理学院

【摘要】 通过对苯-萘、环己烷-萘、水-蔗糖、水-葡萄糖、水-尿素体系的凝固点降低值和溶质在溶剂中溶解快慢进行了反复实验。将测得的摩尔质量与理论摩尔质量值进行比较,得出了(相对)最佳的绿色实验体系。该实验体系已在2013级学生实验中应用,取得了很好的实验效果。同时用精密数字温度温差仪替代贝克曼温度计,以减少污染。进而向学生渗透绿色化学理念。

【Abstract】 By the repeating research of the falling value of freezing point and the dissolving rate of solute in solvent in Benzene-Naphthelene,Cyclohexane-Naphthelene,Water-Sucrose,Water-D-Glucose,Water-Urea systems and by comparing the molar mass that we measured with the theoretical molar mass,we find the best( relatively) green systems( Water-Urea). The green systems have been applied in the experiments of the grade 13 students,and it proved to be a desired result. Meanwhile the precision digital temperature differential instrument is used to replace the Mercury Beckmann thermometer to reduce pollution. Therefore students can get to know the green chemistry better.

  • 【文献出处】 实验室科学 ,Laboratory Science , 编辑部邮箱 ,2016年01期
  • 【分类号】O657.99-4;G642
  • 【被引频次】2
  • 【下载频次】387
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