The application of transition metal hydrides, such as hydrides of Fe, Ru, Ir and Ni, in the activation, hydrogenation, hydroboration and hydrosilation of CO_2 is reported. And the mechanism and the reaction conditions of hydrogenation, hydroboration and hydrosilation of CO_2 are described especially.
【基金】
国家自然科学基金(No.21372143)资助项目~~
【更新日期】
2017-03-21
【分类号】
O643.32
【正文快照】
Received May 20,2016;revised July 19,2016;published online August 12,2016.Project supported by the National Natural Science Foundation of China(No.21372143).过渡金属氢化物是指含有M—H键的一类化合物.自从Hieber在1931年发现了稳定性较差的过渡金属氢化物H2Fe(CO