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ZnO空心微球的制备及光催化性能研究

Synthesis and Photocatalytic Properties of Hollow ZnO Microspheres

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【作者】 陈燕张萍王晓玲

【Author】 CHEN Yan;ZHANG Ping;WANG Xiaoling;School of Chemistry & Chemical Engineering, Xianyang Normal University;

【机构】 咸阳师范学院化学与化工学院

【摘要】 通过二水醋酸锌与吡啶200℃溶剂热反应24h制备出ZnO空心微球。采用X射线衍射仪(XRD)和扫描电子显微镜(SEM)对所制备样品进行了表征。ZnO空心微球形成机理主要遵循Ostwald老化机理。在室温下研究了ZnO空心微球的光催化性能。实验结果表明ZnO空心微球是光降解酸性大红的有效催化剂,其催化过程为准一级反应。

【Abstract】 Hollow ZnO mirospheres were prepared via a facile solvothermal reaction of Zn(Ac)2·2H2O with pyridine solution at 200 ℃ for 24 h. The products were characterized by means of X-ray diffraction(XRD) and scanning electron microscopy(SEM). The hollow microspheres were formed via anOstwald ripening process. Photocatalytic properties of hollow ZnO microspheres were studied at the room temperature. The results indicate that the hollow microspheres display high photocatalytic activity in photodegradation of acid scarlet. The photodegradation of acid scarlet catalyzed by the ZnO microspheres is a pseudo first-order reaction.

【基金】 国家自然科学基金项目(21305117);陕西省自然科学基金项目(2012JQ2014);陕西省教育厅科研基金项目(2010JK894);咸阳师范学院科研基金项目(14XSYK018)
  • 【文献出处】 咸阳师范学院学报 ,Journal of Xianyang Normal University , 编辑部邮箱 ,2016年04期
  • 【分类号】TQ132.41;O643.36
  • 【被引频次】1
  • 【下载频次】91
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