【摘要】 利用氯化铕（Eu Cl3）、苯甲酸（BA）、菲咯啉（Phen）和2,2′-联吡啶（Bipy）为原料合成了Eu（BA）₃Phen和Eu（BA）₃Bipy两种配合物,并将两种配合物分别掺入甲基丙烯酸甲酯（MMA）中,在过氧化苯甲酰（BPO）作用下引发聚合,获得不同探针分子的两种温敏漆Eu（BA）₃Phen/PMMA和Eu（BA）₃Bipy/PMMA。利用红外光谱、紫外吸收光谱和荧光光谱对两种探针分子及温敏漆的特性进行了表征,分析结果表明,探针分子Eu（BA）₃Phen的荧光强度明显强于Eu（BA）₃Bipy,相对应的两种温敏漆Eu（BA）₃Phen/PMMA与Eu（BA）₃Bipy/PMMA均有较好的温度猝灭特性,但是对比分析发现在25³5℃和35⁴5℃温度区间内温敏漆Eu（BA）₃Phen/PMMA的灵敏度较高,而在45⁵5℃和55⁶5℃温度区间内温敏漆Eu（BA）₃Bipy/PMMA的灵敏度较高,可见温敏漆在不同温度区间的测温灵敏度是不同的。更多还原

【Abstract】 In this paper, the probe molecules Eu（BA）₃Phen and Eu（BA）₃Bipy were prepared by using Eu Cl3,Benzoic Acid（BA）, 1,10-Phenanthroline（Phen）, 2,2′-Dipyridyl（Bipy） as raw materials, and two kinds of temperature sensitive paint（Eu（BA）₃Phen/PMMA and Eu（BA）₃Bipy/PMMA） was obtained when Eu（BA）₃Phen and Eu（BA）₃Bipy were doped into the Methyl methacrylate（MMA）, which were polymerized under the action of the initiator Benzoyl peroxide（BPO）. The probe molecules and the TSPs（temperature sensitive paint） were characterized by FTIR, UV-Vis and fluorescence spectra. The results showed that the fluorescence intensity of Eu（BA）₃Phen is stronger than the Eu（BA）₃Bipy, and the temperature quenching properties of the two TSPs were good. Compared to two TSPs, the temperature sensitivity of Eu（BA）₃Phen/PMMA was higher than Eu（BA）₃Bipy/PMMA in 25³5 ℃and 35⁴5 ℃. However, the temperature sensitivity of Eu（BA）₃Bipy/PMMA was higher than Eu（BA）₃Phen/PMMA in 45 ⁵5 ℃ and 55 ⁶5 ℃, that is to say, the temperature sensitivity of TSPs was different in different temperature ranges.更多还原