【摘要】 我们合成了两种典型的磷钼杂多酸盐配合物1和2,并通过X单晶衍射对其结构进行了表征.晶体X-射线衍射结果表明:配合物1以I4(1)/a四方晶系空间群方式结晶,而配合物2以C2/c单斜晶系空间群方式结晶.晶体1和晶体2在ab,bc面上显示了一种二维无限结构.更多还原

【Abstract】 Two typical Keggin phosphomolybdate adduct 1 and 2 have been synthesized and characterized by crystal X-ray diffraction. The crystal X-ray diffraction result shows that complex 1 crystalized in tetragonal system with space group of I4( 1) / a and complex 2 crystalized in monoclinic system with space group of C2 / c. Crystal 1 and 2 show an infinite coordinated two-dimensional structure on ab plane and an infinite coordinated two-dimensional structure on bc plane.更多还原