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可见光响应的高效石墨烯量子点光催化剂(英文)

Graphene quantum dots as efficient, metal-free, visible-light-active photocatalysts

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【作者】 葛介超蓝敏换刘卫敏贾庆岩郭亮周炳江孟祥敏牛广乐汪鹏飞

【Author】 Jiechao Ge;Minhuan Lan;Weimin Liu;Qingyan Jia;Liang Guo;Bingjiang Zhou;Xiangmin Meng;Guangle Niu;Pengfei Wang;Key Laboratory of Photochemical Conversion and Optoelectronic Materials and City U-CAS Joint Laboratory of Functional Materials and Devices,Technical Institute of Physics and Chemistry, Chinese Academy of Sciences;

【机构】 Key Laboratory of Photochemical Conversion and Optoelectronic Materials and City U-CAS Joint Laboratory of Functional Materials and Devices,Technical Institute of Physics and Chemistry, Chinese Academy of Sciences

【摘要】 本文提供了石墨烯量子点的应用新领域.在此前的研究中,我们发现以聚噻吩衍生物(PT2)为前驱物制备的石墨烯量子点在太阳光的照射下可高效产生单线态氧.本文进一步研究发现,此类石墨烯量子点在模拟太阳光的照射下(大于420 nm)可以快速多次降解水中有机污染物和高效灭杀细菌,表明石墨烯量子点在环境保护领域拥有巨大的应用潜力.

【Abstract】 This paper reports on new applications of water-dispersible graphene quantum dots(GQDs) that we recently developed. The prepared GQDs not only show broad absorption in the visible spectrum from 400 to 700 nm, but can also serve as smart photosensitizers with high singlet oxygen(1O2) production under visible-light irradiation(≥420 nm). We showed that the prepared GQDs can potentially be used as a metal-free, visible-light-active, sensitized photocatalyst via energy transfer mechanism, in which the light energy was converted by GQDs to produce 1O2, which can kill nearby microorganisms and degrade organic dyes.

【基金】 supported by the National Natural Science Foundation of China(61227008;51472252;51172244;and 11179006);the Key Research Program of the Chinese Academy of Sciences(KGZD-EW-T02)
  • 【文献出处】 Science China Materials ,中国科学:材料科学(英文版) , 编辑部邮箱 ,2016年01期
  • 【分类号】O643.36
  • 【被引频次】8
  • 【下载频次】247
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