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Formaldehyde gas sensor based on TiO2 thin membrane integrated with nano silicon structure

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【作者】 郑轩明安杰叶丽陈凤华孙西龙刘卫兵李超波欧文王玮冰陈大鹏

【Author】 ZHENG Xuan;MING An-jie;YE Li;CHEN Feng-hua;SUN Xi-long;LIU Wei-bing;LI Chao-bo;OU Wen;WANG Wei-bing;CHEN Da-peng;School of Electronic,Electrical and Communication Engineering,University of Chinese Academy of Sciences;Smart Sensing Research and Development Centre,Institute of Microelectronics,Chinese Academy of Sciences;Laboratory of Advanced Polymer Materials,Institute of Chemistry,Chinese Academy of Sciences;

【机构】 School of Electronic,Electrical and Communication Engineering,University of Chinese Academy of SciencesSmart Sensing Research and Development Centre,Institute of Microelectronics,Chinese Academy of SciencesLaboratory of Advanced Polymer Materials,Institute of Chemistry,Chinese Academy of Sciences

【摘要】 An innovative formaldehyde gas sensor based on thin membrane type metal oxide of Ti O2 layer was designed and fabricated. This sensor under ultraviolet(UV) light emitting diode(LED) illumination exhibits a higher response to formaldehyde than that without UV illumination at low temperature. The sensitivities of the sensor under steady working condition were calculated for different gas concentrations. The sensitivity to formaldehyde of 7.14 mg/m3 is about 15.91 under UV illumination with response time of 580 s and recovery time of 500 s. The device was fabricated through micro-electro-mechanical system(MEMS) processing technology. First, plasma immersion ion implantation(PIII) was adopted to form black polysilicon, then a nanoscale TiO2 membrane with thickness of 53 nm was deposited by DC reactive magnetron sputtering to obtain the sensing layer. By such fabrication approaches, the nanoscale polysilicon presents continuous rough surface with thickness of 50 nm, which could improve the porosity of the sensing membrane. The fabrication process can be mass-produced for the MEMS process compatibility.

【Abstract】 An innovative formaldehyde gas sensor based on thin membrane type metal oxide of Ti O2 layer was designed and fabricated. This sensor under ultraviolet(UV) light emitting diode(LED) illumination exhibits a higher response to formaldehyde than that without UV illumination at low temperature. The sensitivities of the sensor under steady working condition were calculated for different gas concentrations. The sensitivity to formaldehyde of 7.14 mg/m3 is about 15.91 under UV illumination with response time of 580 s and recovery time of 500 s. The device was fabricated through micro-electro-mechanical system(MEMS) processing technology. First, plasma immersion ion implantation(PIII) was adopted to form black polysilicon, then a nanoscale TiO2 membrane with thickness of 53 nm was deposited by DC reactive magnetron sputtering to obtain the sensing layer. By such fabrication approaches, the nanoscale polysilicon presents continuous rough surface with thickness of 50 nm, which could improve the porosity of the sensing membrane. The fabrication process can be mass-produced for the MEMS process compatibility.

【基金】 supported by the National Natural Science Foundation of China(Nos.61335008,61274119 and 61306141);the National High Technology Research and Development Program of China(No.2015AA042605);the Natural Science Foundation of Jiangsu Province(No.BK20131099)
  • 【文献出处】 Optoelectronics Letters ,光电子快报(英文版) , 编辑部邮箱 ,2016年04期
  • 【分类号】TP212
  • 【被引频次】3
  • 【下载频次】62
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