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表面Ni-Co/WC复合熔覆层的组织与三点弯曲性能

Microstructure and bending behavior of Ni-Co/WC composite coatings on ZG45 steel deposited by vacuum sintering cladding

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【作者】 王旭升杨贵荣宋文明李健马颖郝远

【Author】 WANG Xu-sheng;YANG Gui-rong;SONG Wen-ming;LI Jian;MA Ying;HAO Yuan;State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals,Lanzhou University of Technology;Lanpec Technologies Limited;Wuhan Research Institute of Materials Protection;

【机构】 兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室甘肃蓝科高新石化装备股份有限公司武汉材料保护研究所

【摘要】 在ZG45表面采用真空熔覆技术制备了Ni-Co/WC复合熔覆层,通过SEM、EPMA和XRD观察并分析了熔覆层的显微组织结构和相组成,通过三点弯曲试验研究了熔覆层的弯曲行为,并分析了断口形貌和断裂机理。结果表明,WC颗粒在镍-钴基合金中呈现网状分布,熔覆层的主要组成相有WC、Cr7C3、Cr23C6、Ni3Si、Fe Ni3和镍-钴基固溶体;三点弯曲试验表明,Ni-Co基合金熔覆层与基体结合良好,即使熔覆层朝下承受拉应力时试样自拉应力最大的熔覆层表面开始产生延伸至基体内的纵向裂纹,并无沿结合界面的横向裂纹,而Ni-Co/WC复合熔覆层却在弯曲过程中与基体沿界面发生剥离;断裂试样的基体断口有大量韧窝,基体区域属于韧性断裂,而Ni-Co/WC复合熔覆层的断裂方式包括穿晶断裂和沿晶断裂。

【Abstract】 The Ni-Co / WC composite coatings were fabricated on ZG45 steel by vacuum sintering cladding.Microstructure and composition of the composite coatings were characterized by SEM,EPMA and XRD.The bending behavior and bending strength of the composite coatings were studied by three-point bending test.The results show that the WC particles are distributed in the Ni-Co alloy matrix forming a special 3D reticular microstructure.The main phases of the composite coatings are WC,Cr7C3,Cr23C6,Ni3 Si,Fe Ni3 and nickel and cobalt based solid solution.Three point bending test results show that the Ni-Co / WC composite coatings peel off along the interface between the coating and substrate,however,no transverse cracking is observed along the interface between the coating and substrate for the Ni-Co alloy coatings in the tension stress state.The dimple fracture morphology shows the ductile facture mechanism for the substrate,and the facture of the Ni-Co / WC composite coatings exhibits mixed- rupture characteristics of transgranular and intergranular fracture.

【基金】 国家自然科学基金(51205178);甘肃省自然科学基金(1208RJZA189)
  • 【文献出处】 材料热处理学报 ,Transactions of Materials and Heat Treatment , 编辑部邮箱 ,2016年10期
  • 【分类号】TG174.4
  • 【被引频次】2
  • 【下载频次】188
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