【摘要】 以二茂铁、乙酸酐和无水乙二胺等为原料,合成双(乙酰基二茂铁)缩乙二亚胺合铜,并对其进行了IR、MS表征。实验考察了反应温度、反应时间以及反应物配比对结果的影响。当反应温度为60℃,反应时间为4h,双(乙酰基二茂铁)缩乙二亚胺与二水合氯化铜的物质的量之比为1∶3时,最高收率为88.9%。更多还原

【Abstract】 Bis(acetylferrocene)ethylenediimine copper(Ⅱ)was synthesized using ferrocene,acetic anhydride and ethylenediamine as raw materials and identified by IR and MS spectroscopy.The effects of mole ratio,reaction temperature and time on the productivity were investigated.The results showed that under the conditions of the mol ratio of bis(acetylferrocene)ethylenediimine∶cupric nitrate=1∶3,reaction temperature 60 ℃,and reaction time 4h,the highest yield of 88.9% was obtained.更多还原