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氯化聚氯乙烯酸相法生产工艺及其稳定性研究

Study on Chlorination of Polyvinyl Chloride by Acid Phase Method

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【作者】 刘云华刘旭思

【Author】 LIU Yun-hua;LIU Xu-si;College of chemistry and chemical engineering and materials science,Shandong Normal University;Shandong Asahi Industry New Material Co.,Ltd.;

【机构】 山东师范大学化学化工与材料科学学院山东旭业新材料有限公司

【摘要】 氯化聚氯乙烯(CPVC)酸相法生产工艺是通过用一定浓度的盐酸介质替代水介质进行的氯化反应,使氯化反应的均匀性提高,产品氯含量稳定,热稳定性明显提高。通过控制通气量及反应时间等反应参数,可以得到不同氯含量及其他性能参数的氯化聚氯乙烯(CPVC),产品满足不同的需要。本工艺方法简单、生产效率高、产品均匀性和稳定性好。

【Abstract】 Polyvinyl chloride( CPVC) is chlorinated by acid phase method,which is processed by alternative water medium in chlorination reaction with a certain concentration of hydrochloric acid. The uniformity of chlorination,chlorine content and the inherent quality of the product was investigated. By controlling the ventilation amount and reaction time in the reaction a series of chlorinated polyvinyl chloride products with different chlorine content and performances were obtained,which adapt to the needs of different occasions. The result showed that the acid phase method is a simple process,high efficiency,uniformity of chlorination,good stability and energysaving.

  • 【文献出处】 合成材料老化与应用 ,Synthetic Materials Aging and Application , 编辑部邮箱 ,2016年02期
  • 【分类号】TQ325.3
  • 【被引频次】1
  • 【下载频次】225
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