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高填充石膏/PVC共混体系流变性研究

Research on Rheology of High- load Gypsum/PVC Blend System

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【作者】 马蓬杨谢卫苹陈浩远梁吉张峰榛向兰

【Author】 MA Peng-yang;XIE Wei-ping;CHEN Hao-yuan;LIANG Ji;ZHANG Feng-zhen;XIANG Lan;Department of Chemical Engineering,Tsinghua University;Department of Mechanical Engineering,Tsinghua University;School of Chemical Engineering,Sichuan University of Science & Engineering;

【机构】 清华大学化学工程系清华大学机械工程系四川理工学院化学工程学院

【摘要】 文章研究了高填充(石膏填充量≥50%)条件下共混温度、石膏填充量及增塑剂对石膏/PVC共混体系流变性的影响。共混温度提高导致体系流变性先升后降,180℃~190℃最佳;石膏填充量从150 phr提至350 phr时,平衡转矩提高80%;加入增塑剂可提高体系流变性,降低材料弯曲强度。在石膏填充量350 phr,增塑剂加入量20 phr及180℃条件下,制得弯曲强度28.4 MPa的高填充石膏/PVC复合材料。

【Abstract】 The influence of blend temperature,loading of gypsum and plasticizer on rheology of gypsum / PVC blend system with a loading of gypsum≥50% was studied in the paper. The increase of temperature from 160 ℃ to 200 ℃ led to the initial increase and the subsequent rheology decrease of the blend system,which optimum temperature was 180 ℃ ~ 190 ℃. The increase of gypsum from 150 phr to 350 phr led to the increase of the balance torque by 80%. The addition of plasticizer led to increase of the rheology and decrease of the flexural strength of gypsum / PVC blend system. High load gypsum / PVC composite composed of 350 phr of gypsum and 20 phr of plasticizer and with a flexural strength of 28. 4 MPa was fabricated at 180℃.

【关键词】 石膏PVC流变性增塑剂
【Key words】 gypsumPVCrheologyplasticizer
【基金】 国家自然科学基金(No.51234003);国家科技支撑计划(2013BAC14B02);山西省煤基重点科技攻关项目(MC2014-06)
  • 【文献出处】 盐业与化工 ,Journal of Salt and Chemical Industry , 编辑部邮箱 ,2016年09期
  • 【分类号】TB332
  • 【被引频次】1
  • 【下载频次】163
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