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紫外/PS、紫外/H2O2降解2-MIB和土臭素对比

Comparative Study on UV/Persulfate and UV/Hydrogen Peroxide for Degradation of 2-MIB and Geosmin

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【作者】 岳思阳张爱红谢鹏超王宗平马军

【Author】 YUE Si-yang;ZHANG Ai-hong;XIE Peng-chao;WANG Zong-ping;MA Jun;Design and Research Institute of Architecture and Urban Planning,Huazhong University of Science and Technology;School of Environmental Science and Engineering,Huazhong University of Science and Technology;School of Municipal and Environmental Engineering,Harbin Institute of Technology;

【机构】 华中科技大学建筑与城市规划设计研究院华中科技大学环境科学与工程学院哈尔滨工业大学市政环境工程学院

【摘要】 紫外/过氧化氢(UV/H2O2)和紫外/过硫酸盐(UV/PS)均可有效降解纯水体系中的2-甲基异莰醇(2-MIB)和土臭素(GSM),且UV/PS的降解效果更优。重碳酸根和天然有机物均可以显著抑制UV/H2O2和UV/PS降解2-MIB和GSM的效能,但对UV/PS体系的抑制作用显著强于其对UV/H2O2体系的抑制作用,结果导致UV/H2O2在重碳酸根或者天然有机物存在时降解2-MIB和GSM的效果优于UV/PS体系。由于实际水体中通常含有较高浓度的重碳酸根和天然有机物,因此UV/H2O2降解松花江水体中2-MIB和GSM的效果优于UV/PS体系。通过此研究可知UV/H2O2相对于UV/PS更适于实际水体中2-MIB和GSM的去除。

【Abstract】 Both ultraviolet/hydrogen peroxide( UV/H2O2) and ultraviolet/persulfate( UV/PS)are effective in the degradation of 2-methylisoborneol( 2-MIB) and geosmin( GSM) in pure water. The degradation efficiency of UV/PS was better than that of UV/H2O2. Both bicarbonate and natural organic matter( NOM) could inhibit the removal of 2-MIB and GSM significantly. However,the inhibition effect on UV/PS system was more significant than that on UV/H2O2 system,resulting in a fact that UV/H2O2 showed higher removal efficiencies of 2-MIB and GSM than UV/PS system in the presence of bicarbonate or NOM. Due to the high contents of bicarbonate and NOM in real water,UV/H2O2 was more effective than UV/PS in the degradation of 2-MIB and GSM contained in Songhua River water. This study suggested that UV/H2O2 might be a better choice than UV/PS when treating 2-MIB and GSM in real water.

【基金】 国家自然科学基金资助项目(5157081665)
  • 【文献出处】 中国给水排水 ,China Water & Wastewater , 编辑部邮箱 ,2016年19期
  • 【分类号】TU991.2
  • 【被引频次】13
  • 【下载频次】302
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