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石英岩尾砂的表面改性及其对砂浆强度和干燥收缩的影响

Surface modification of quartz tailing and its effecton strength and drying shrinkage of cement mortars

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【作者】 陈登邓敏郝成伟兰祥辉莫立武

【Author】 CHEN Deng;DENG Min;HAO Chengwei;LAN Xianghui;MO Liwu;State Key Laboratory of Materials Oriented Chemical Engineering,College of Materials Science and Engineering,Nanjing Tech University;Colloge of Architecture and Civil Engineering,West Anhui University;

【机构】 南京工业大学材料科学与工程学院材料化学工程国家重点实验室皖西学院建筑与土木工程学院

【摘要】 采用电石渣对石英岩尾砂进行煅烧改性,利用X射线衍射仪、背散射扫描电镜和能谱分析等分析方法对改性石英岩尾砂矿物组成和微观结构进行表征,并测定了掺改性石英岩尾砂的水泥砂浆强度和干燥收缩。通过背散射扫描电镜和压汞仪研究了掺改性石英岩尾砂水泥砂浆的微观结构。结果表明,改性石英岩尾砂颗粒表面生成了具有水化活性的β-C2S,水化生成CSH凝胶,可以改善石英岩尾砂与水泥浆体的界面结构,降低了水泥砂浆的孔隙率和干燥收缩,提高了掺改性石英岩尾砂水泥砂浆的抗压强度。

【Abstract】 The surface of quartz tailing was modified by calcination method through mixing with carbide slag.The mineral composition and microstructure of the modified quartz tailing were analyzed by using X-ray diffraction(XRD),backscattered electron microscopy(BSEM)and energy dispersive spectrometer(EDS).The effects of modified quartz tailing on the drying shrinkage and compressive strength of cement mortars were investigated.The microstructure of cement mortars was analyzed by using BSEM and mercury intrusion porosimetry(MIP).The results show that the β-C2S phases were formed on the surface of the modified quartz tailings.Due to the hydration of the β-C2S,CSH gel was generated,the interface between cement paste and quartz tailing was densified,the porosity and drying shrinkage of cement mortars with the modified quartz tailing was decreased,and the compressive strength of cement mortars was increased.

【基金】 江苏高校优势学科建设工程资助项目(PAPD);长江学者和创新团队发展计划资助项目(IRT1146);安徽省高等学校省级自然科学研究重点资助项目(KJ2013A257);南京工业大学材料化学国家重点实验室开放课题基金资助项目(KL12-12)
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,2016年10期
  • 【分类号】TU578.1
  • 【被引频次】1
  • 【下载频次】145
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