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钼网衬底上大面积硅纳米线的制备及其光催化性能研究

Large-scale Synthesis of Silicon Nanowires on Molybdenum Nets for High-efficiency Photodegradation

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【作者】 黄奔李玄泽王磊夏静朱丹丹孟祥敏

【Author】 HUANG Ben;LI Xuanze;WANG Lei;XIA Jing;ZHU Dandan;MENG Xiangmin;Key Laboratory of Photochemical Conversion and Optoelectronic Materials,Technical Institute of Physics and Chemistry,Chinese Academy of Sciences;

【机构】 中国科学院理化技术研究所光化学与光功能材料重点实验室

【摘要】 硅纳米材料广泛应用于光功能导向的各个领域,发展针对光功能应用及一维硅纳米结构的规模化可控制备方法,实现硅纳米结构的宏量制备,将为硅纳米结构的应用提供材料保障。本文采用简单的化学气相沉积法成功地在Mo网衬底上制备了大面积的硅纳米线(SiNWs),并通过扫描电子显微镜、透射电子显微镜、X射线粉末衍射仪、拉曼光谱仪,对制备的SiNWs进行了详细的研究。通过在低功率紫外光照射下SiNWs对罗丹明B和甲基蓝的光降解能力的研究,发现在Mo网衬底上生长的SiNWs对于有机染料具有很好的降解能力。

【Abstract】 Si nano-materials are wildly used in the field of photocatalyst,solar cell,photodetector due to their excellent photo-absorption ability.So the controlled and large-scale synthesis of one dimensional Si nanomaterials becomes the key which affects their applications.In this report,we used a simple chemical vapor deposition(CVD)method to grow large-scale Si nanowires(SiNWs)on molybdenum(Mo)nets substrate.And the characteristics of SiNWs were detailedly analyzed by scanning electron microscope,transmission electron microscope,X-ray diffraction and Raman spectrum.Moreover,the photocatalytic properties of as-grown SiNWs were examined by the photodegradation of Rhodamine B and Methylene Blue under low power ultraviolet(UV)light.In addition,the results show that SiNWs growing on Mo nets substrate have a high photodegration efficient for organic dyes.

【基金】 国家重点基础研究发展规划项目(973项目,2012CB932401);中国科学院战略性先导科技专项(XDA09040203)资助
  • 【文献出处】 影像科学与光化学 ,Imaging Science and Photochemistry , 编辑部邮箱 ,2016年03期
  • 【分类号】O643.36;TB383.1
  • 【被引频次】3
  • 【下载频次】78
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