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加热析出法制备纳米纤维素及其性能

Fabrication and Property of Low Crystallinity Nanocellulose by Heating the Cellulose Solution

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【作者】 楼宏铭邱珂贤祝都明林吼坑

【Author】 Lou Hong-ming;Qiu Ke-xian;Zhu Du-ming;Lin Hou-keng;College of Chemistry and Chemical Engineering,South China University of Technology;State Key Laboratory of Pulp and Paper Engineering,South China University of Technology;

【机构】 华南理工大学化学与化工学院华南理工大学制浆造纸工程国家重点实验室

【摘要】 纳米纤维素是一种新型高分子功能材料,具有独特的结构和优异的性能。本文采用加热析出法制备得到纳米纤维素(HNC)的直径为10-100 nm,XRD、FTIR、TG等测试结果表明HNC在制备过程中,纤维素晶体由I型转化为II型,但分子结构未发生变化。通过对纳米纤维素分散液进行压滤制备得到纳米纤维素膜(HNCF),其透光率为89.7%,抗拉强度为84.9 MPa,杨氏模量为4933.6 MPa。并进一步揭示了加热析出法制备纳米纤维素的机理。

【Abstract】 Nanocellulose(HNC) is a novel functional polymer material with unique structure and excellent performance. HNC with a width between 10-100 nm was prepared by heating cellulose solution directly. The structure of HNC did not change during the preparation process,but the crystal form transferred from Cellulose I to Cellulose II,which was validated by the results of XRD,FTIR,and thermal performance test. The nanocellulose film(HNCF) obtained by filtering the nanocellulose solution,which showed a transmittance of 89. 7%,tensile strength of 84. 9 MPa and Young’s modulus of 4933. 6 MPa,respectively. The convincing mechanism model explaining the function of sodium hydroxide and urea was revealed.

【关键词】 纳米纤维素加热析出性能
【Key words】 nanocelluloseheatingproperty
【基金】 国家自然科学基金资助项目(21376100);国家重点基础研究发展计划(973计划;2012CB215302)
  • 【文献出处】 造纸科学与技术 ,Paper Science & Technology , 编辑部邮箱 ,2016年06期
  • 【分类号】TQ352.79
  • 【被引频次】1
  • 【下载频次】182
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