【摘要】 以氨水为工质对的吸收式制冷循环和热泵技术中,分离氨和水时需要大量能耗。本文将离子液体P（CH₃）₄Cl作为添加剂加入氨水中,组成分离能耗较低的三元工质体系。利用等温合成法实验系统,测定了NH₃-H₂O-P（CH₃）₄Cl体系在温度范围293.15³33.15 K、压力范围0⁷00 kPa.时的气液相平衡数据;然后采用扩展的Antoine方程对实验数据进行拟合,得到了可靠的拟合精度和方程的模型参数;最后,基于相平衡比讨论P（CH₃）₄Cl的添加效果,测定密度和黏度数据,作为进一步开发该工质体系的参考。更多还原

【Abstract】 In traditional absorption refrigeration cycle and heat pump technologies based on NH₃-H₂O working pair,high energy consumption occurs when vapor NH3 was separated from solution.This work proposed ionic liquid P（CH₃）₄Cl as additive to compose ternary working fluids and to reduce the energy consumption of rectification.The vapor-hquid equilibrium data of NH₃-H₂O-P（CH₃）₄Cl system was measured by the isothermal synthesis method under temperature of 293.15³33.15 K and pressure of 0⁷00 kPa.Then the data was fitted by an extended Antoine equation,the model parameters of which were calculated with good accuracy.Finally,the addition effect and development potential of P（CH₃）₄Cl were evaluated by the phase equilibrium ratio,density,and viscosity data.更多还原