Preparation and photoluminescence properties of Dy³⁺-doped Ba₃Lu（PO₄）₃ phosphors

【摘要】 Ba₃Lu（PO₄）₃:Dy³⁺ phosphors were successfully synthesized by conventional solid state reaction and its photoluminescence properties were investigated by X-ray diffraction（XRD）,photoluminescence spectra and diffuse reflectance spectra,respectively.Results showed that the phosphor could be excited by the ultraviolet visible light in the region from 320 to 460 nm,and it showed two dominant emission bands peaking at 484 nm（blue light） and 575 nm（yellow light） which originated from the transitions of⁴F_9/2→⁶H_15/2 and ⁴F_9/2→⁶H_13/2 of Dy³⁺,respectively.According to Dexter’s theory,the concentration quenching mechanism occurred via the electric dipole-dipole interaction.The lifetime values of Dy³⁺ ions at different concentrations（x=0.01,0.03,0.05,0.08 and0.10） were determined to be about 0.8556,0.7595,0.6864,0.6059 and 0.5456 ms.更多还原

【Abstract】 Ba₃Lu（PO₄）₃:Dy³⁺ phosphors were successfully synthesized by conventional solid state reaction and its photoluminescence properties were investigated by X-ray diffraction（XRD）,photoluminescence spectra and diffuse reflectance spectra,respectively.Results showed that the phosphor could be excited by the ultraviolet visible light in the region from 320 to 460 nm,and it showed two dominant emission bands peaking at 484 nm（blue light） and 575 nm（yellow light） which originated from the transitions of⁴F_9/2→⁶H_15/2 and ⁴F_9/2→⁶H_13/2 of Dy³⁺,respectively.According to Dexter’s theory,the concentration quenching mechanism occurred via the electric dipole-dipole interaction.The lifetime values of Dy³⁺ ions at different concentrations（x=0.01,0.03,0.05,0.08 and0.10） were determined to be about 0.8556,0.7595,0.6864,0.6059 and 0.5456 ms.更多还原