【摘要】 以希夫碱衍生物4-氨基安替比林缩吡啶-4-甲醛为配体(L),采用溶剂热合成法,成功合成了2个Schiff碱Co(Ⅱ)配合物[Co LCl2](1)、Mn(Ⅱ)配合物[Mn LCl2](2),通过元素分析、红外光谱IR、XRD、TG和磁性分析等测试手段对2个配合物进行表征,并用X-射线单晶衍射测得Co(Ⅱ)、Mn(Ⅱ)配合物的晶体结构。单晶结构表明,配合物1的晶体属于单斜晶系,空间群为Cc;配合物2的晶体属于三斜晶系,空间群为P1。配合物1是以Co(Ⅱ)为中心的扭曲四面体构型,配合物2是以Mn(Ⅱ)为中心的扭曲八面体构型。更多还原

【Abstract】 Two complexes [Co LCl2](1) and [Mn LCl2](2)(L=4-(4-pyridinemethyleneamino)-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one) were solvothermally synthesized and structurally characterized by elemental analysis,IR, XRD, TG, single-crystal X-ray diffraction and magnetic analysis. The complexes 1 and 2 are determined by X-ray structural analysis and the structure parameters are analyzed as follows: 1, monoclinic, Cc; 2, triclinic, P1.The X-ray diffraction results suggest that the complex 1 exhibits distorted tetrahedral configuration, and the complex 2 exhibits distorted octahedral configurations. CCDC: 913873, 1; 913872, 2.更多还原