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咪唑离子液体对四尾栅藻的毒性

Toxicity of imidazolium- based ionic liquids to Scenedesmus quadricauda

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【作者】 吴洁陈晓娣邓芸朱凯韩萍芳顾军

【Author】 WU Jie;CHEN Xiaodi;DENG Yun;ZHU Kai;HAN Pingfang;GU Jun;College of Biotechnology and Pharmaceutical Engineering,Nanjing Tech University;Kunshan Innovation Institute of Nanjing University;School of Physics,Nanjing University;

【机构】 南京工业大学生物与制药工程学院南京大学昆山创新研究院南京大学物理学院

【摘要】 按照藻类生长抑制试验标准方法,以四尾栅藻为受试生物,研究了离子液体1-丁基-3-甲基咪唑氯盐([C4mim][Cl])和1-丁基-3-甲基咪唑四氟硼酸盐([C4mim][BF4])对四尾栅藻的影响,测定了半数有效浓度(EC50)和叶绿素含量。结果表明:[C4mim][Cl]和[C4mim][BF4]对四尾栅藻的生长和叶绿素的产生均具有抑制作用,毒性效应随着浓度的增大和培养时间的增长而增加,96 h的EC50分别为57.8和38.8 mg/L。离子液体质量浓度为200mg/L时,四尾栅藻的叶绿素总量仅为对照组的32%和26%。此结果可以说明离子液体对生态系统存在潜在的负面效应。

【Abstract】 Toxic effects of ionic liquids 1-butyl-3-methylimidazolium chloride([C4mim][Cl]) and 1-butyl-3-methylimidazolium tetrafluoroborate([C4mim][BF4]) on Scenedesmus quadricauda were studied by using alga growth inhibition test.Two endpoints EC50 values and chlorophyll contents were determined.The results indicate that [C4mim][Cl] and [C4mim][BF4]limited the growth and chlorophyll content of S.quadricauda,the toxic effects increased with the concentration and incubation time.The 96 h EC50 was 57.8 and 38.8 mg/L,respectively.When adding 200mg/L ionic liquid,the total chlorophyll content of S.quadricauda were only 32% and 26% respectively,compared with the control group.Our findings imply the potential adverse effect of ionic liquids on the ecological system.

【基金】 江苏省自然科学基金(BK2012218)
  • 【文献出处】 生物加工过程 ,Chinese Journal of Bioprocess Engineering , 编辑部邮箱 ,2015年02期
  • 【分类号】X171.5
  • 【被引频次】4
  • 【下载频次】109
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