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溶剂热法合成有机金属框架材料Co₂（C₈O₆H₄）₂·4H₂O

Synthesis and crystal structure of a novel coordination polymer Co₂[（C₈O₆H₄）₂·（H₂O）₄]

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【Author】 CAI Liangze;ZHENG Jianhong;ZENG Yanting;WU Xiuwen;LIN Mei;WANG Lihua;College of Chemistry and Chemical Engineering,Fujian Normal University;

【机构】福建师范大学化学与化工学院；

【摘要】采用溶剂热法合成了一种新的金属有机配合物[Co2(C8O6H4)2·(H2O)4],通过X射线单晶衍射技术对该化合物进行了结构表征。结果表明,该化合物晶体属三斜晶系,空间群为P1;晶胞参数a=9.389(2)(1=10-10 m),b=9.421(3),c=12.209(3);α=101.846(2)°;β=104.453(2)°;γ=105.305(3)°;V=965.23;Z=2;Dc=2.003g/cm3,μ=1.810mm-1,F(000)=588,GooF=1.044,R1=0.0268,ωR2=0.023 0[I>2σ(I)]。更多还原

【Abstract】 A new metal organic coordination polymer Co2[(C8O6H4)2·(H2O)4]is systhesized and characterized by infrared spectroscopy and X ray diffraction.The title compound is crystallized in triclinic system,space group P1,a=9.389(2)(1=10-10 m),b=9.421(3),c=12.209(3);α=101.846(2)°;β=104.453(2)°;γ=105.305(3)°;V=965.23;Z=2;Dc=2.003g/cm3,μ=1.810mm-1,F(000)=588,GooF=1.044,R1=0.026 8,ωR2=0.023 0[I>2σ(I)].更多还原