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喹啉表面活性剂自组装制备多功能介孔材料及传感性能研究
Synthesis and Sensing Properties Study of Multifunctional Mesoporous Materials by Quinoline-surfactant Self-assembling
【摘要】 通过喹啉功能化的表面活性剂自组装和配位作用,制备多功能介孔材料,并研究了其在离子检测中的应用。采用N2吸附、X射线衍射、红外光谱、荧光光谱等手段对材料进行表征。实验结果表明,介孔硅孔道内喹啉表面活性剂与Al3+配位生成具有很强发光性能的荧光材料,该材料可以选择性的识别移除焦磷酸。
【Abstract】 The multifunctional mesoporous materials were fabricated by using quinoline- surfactant self- assembly approach and coordination role. The application of multifunctional mesoporous materials in the ion detection was investigated. The materials were characterized by N2 adsorption,X- ray diffraction,infrared spectrum,fluorescent spectroscopy,and so on.Experimental results showed that quinoline- surfactant coordinated with Al3 +in the porous silicate channels could generate fluorescence materials,which have high luminous performance. The fluorescence materials could be used to selectively identify and remove pyrophosphate.
【Key words】 surfactant self-assembling; mesoporous silica materials; magnetism; fluorescence; sensing property;
- 【文献出处】 山东化工 ,Shandong Chemical Industry , 编辑部邮箱 ,2015年11期
- 【分类号】O647.2;TB383.4
- 【下载频次】87