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喹啉表面活性剂自组装制备多功能介孔材料及传感性能研究

Synthesis and Sensing Properties Study of Multifunctional Mesoporous Materials by Quinoline-surfactant Self-assembling

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【作者】 王婵邢国秀于忠玺刘诗丽

【Author】 Wang Chan;Xing Guoxiu;Yu Zhongxi;Liu Shili;Yantai Shandong Center for Integrated Technology Transfer Center,Chinese Academy of Sciences;School of Chemistry and Materials Science,Ludong University;

【机构】 中国科学院山东综合技术转化中心烟台中心鲁东大学化学与材料科学学院

【摘要】 通过喹啉功能化的表面活性剂自组装和配位作用,制备多功能介孔材料,并研究了其在离子检测中的应用。采用N2吸附、X射线衍射、红外光谱、荧光光谱等手段对材料进行表征。实验结果表明,介孔硅孔道内喹啉表面活性剂与Al3+配位生成具有很强发光性能的荧光材料,该材料可以选择性的识别移除焦磷酸。

【Abstract】 The multifunctional mesoporous materials were fabricated by using quinoline- surfactant self- assembly approach and coordination role. The application of multifunctional mesoporous materials in the ion detection was investigated. The materials were characterized by N2 adsorption,X- ray diffraction,infrared spectrum,fluorescent spectroscopy,and so on.Experimental results showed that quinoline- surfactant coordinated with Al3 +in the porous silicate channels could generate fluorescence materials,which have high luminous performance. The fluorescence materials could be used to selectively identify and remove pyrophosphate.

【基金】 国家自然科学基金(21306074)
  • 【文献出处】 山东化工 ,Shandong Chemical Industry , 编辑部邮箱 ,2015年11期
  • 【分类号】O647.2;TB383.4
  • 【下载频次】87
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