【摘要】 以双环戊二烯为起始原料,经Diels-Alder反应、还原反应及酯化反应,合成得到双三氟甲磺酸亚降冰片烯-5基-二甲酯.选择毒性较低、易于得到的三氟甲磺酰氯做原料,去除有毒有害吡啶试剂的使用,保证无水无氧的环境,使得反应进行更彻底,得到的产物更纯净.更多还原

【Abstract】 Di-trifluoromethanesulfonate sub-norbornene-5-dimethylester was synthesized by dicyclopentadiene and 5-norbornene-2,3-dicarboxylic anhydride via Diels-Alder reaction, reduction reaction and esterification reaction. Trifluoromethanesulfonylchloride was used which was comparatively low toxicity and easy to buy as raw material. Toxic pyridine was not used in the experiment.更多还原