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高氟选矿废水的吸附净化技术研究

Research on Adsorption and Purification Technology for Fluorinion from Mineral Processing Wastewater

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【作者】 王恩文郭振华雷绍民张世春钟乐乐

【Author】 WANG Enwen;GUO Zhenhua;LEI Shaomin;ZHANG Shichun;ZHONG Lele;School of Resources and Environmental Engineering,Wuhan University of Technology;School of Resources and Environmental Engineering,Anshun University;Henan Jiayu Environment Scientific & Technology Company;

【机构】 武汉理工大学资源与环境工程学院安顺学院资源与环境工程学院河南佳昱环境科技有限公司

【摘要】 以含有Si、Al、Ca、C元素的矿物材料作为基质,经特定条件处理制备成轻质多孔吸附材料(LMAM)。研究了该吸附材料对含氟量较高的石英纯化废水的吸附性能。结果表明,当振荡频率为105r獉min-1,轻质多孔吸附材料用量为20g獉L-1,pH为8.0,常温下反应时间90min时,废水ρ(F-)由吸附净化前的3590 mg獉L-1降为118.47mg獉L-1,pH为7.3。LMAM对石英纯化废水中F-的吸附机制研究表明,吸附体系均符合Langmiur吸附等温线模型及准一级动力学模型/准二级动力学模型。

【Abstract】 A low-density and multi-porous adsorption material(LMAM)was made from several mineral materials which contain elements of Si,Al,Ca and C by a special treatment.And the adsorption and purification capacity of LMAM on fluorinion from quartz processing wastewater was investigated.The results showed that the residual concentration of fluorinionρ(F-)decreased from 3590 mg獉L-1 to 118.47mg獉L-1 and pH value reduced to 7.3under the vibrating frequency of 105r獉min-1,adsorbent dosage of 20g獉L-1,pH of 8.0and reacting time of 90 min at ordinary temperature.The LMAM adsorption mechanism followed Langmuir isothermal curves model and typical pseudo-first-order/pseudo-second-order kinetic models for the removal of fluorinion from quartz processing wastewater.

【基金】 贵州省科学技术厅;安顺市人民政府;安顺学院联合科技基金项目(黔科合J字LKA[2012]10号);江苏省科技厅科技基础设施建设计划项目(BM2010480)
  • 【文献出处】 矿业研究与开发 ,Mining Research and Development , 编辑部邮箱 ,2015年10期
  • 【分类号】X751
  • 【被引频次】6
  • 【下载频次】119
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