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高铌TiAl合金中Nb偏析区的相变规律

Phase transformations of Nb microsegregation zone in high Nb containing TiAl alloy

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【作者】 徐向俊宋霖梁永峰林均品

【Author】 XU Xiang-jun;SONG Lin;LIANG Yong-feng;LIN Jun-pin;School of Materials and Chemistry,Zhongyuan University of Technology;State Key Laboratory for Advanced Metals and Materials,University of Science and Technology Beijing;

【机构】 中原工学院材料与化工学院北京科技大学新金属材料国家重点实验室

【摘要】 通过扫描和透射电镜研究了铸造Ti-45Al-8Nb-0.2W-0.2B-0.02Y合金中Nb偏析区的相结构及其经中温和高温热处理后的相变规律。结果表明,铸造合金中的偏析区由约1μm大小的ωo相(B82结构)及其所在的βo(B2结构)与细小的ω相关相混杂而成的基体组成。中温较长时间处理后合金的Nb偏析区部分转变为γ相,已经发现3种βo(ω)→γ相变机制,即由基体的片层外延生长成为等轴γ、βo直接形成γ以及与已经存在的γ形成真孪晶后向βo推进。剩余偏析区表现为βo内分布着ωo或表现为纯的βo相。高温较短时间处理可以消除Nb偏析区,使偏析区由βo及ωo相关相转变为α2相。

【Abstract】 Phases and transformation behavior of Nb-microsegregation zone after heat treated at medium and high temperature of Ti-45Al-8Nb-0. 2W-0. 2B-0. 02 Y alloy were analyzed by SEM and TEM. The results show that in the as-cast alloy,the Nb-microsegregation zone is consisted of micron-level ωophase( B82structure) distributing within a blurry mixture of βo( B2 structure) and ω-related phase. After heat treatment at medium temperature for a long time,γ phase forms in parts of the Nb-microsegregation zone by three mechanics,the coarsening growth of γ lamella in lamellar colonies,directly transforming from the βophase to γ phase and forming true-twin of the preexisting γ. The retained Nb-microsegregation zone exhibits ωodistributed βoor nearly pure βo. After heat treated at high temperature,Nbmicrosegregation zone is eliminated and the original βoand ω-related phases transform to α2phase.

【基金】 国家自然科学基金(U1204508);国家重点基础研究发展(973)计划(2011CB605501)
  • 【文献出处】 材料热处理学报 ,Transactions of Materials and Heat Treatment , 编辑部邮箱 ,2015年08期
  • 【分类号】TG146.23
  • 【被引频次】4
  • 【下载频次】308
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