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[Cu₃（hssal）₂（phen）₂（H₂O）₄]配合物的合成、性质和作为前驱体合成CuO的研究

Synthesis,properties of [Cu₃（hssal）₂（phen）₂（ H₂O）₄] complex and as a precursor producing micro-sized CuO particle

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【Author】 LI Qiang;JIANG Min;WU Gang;College of Material and Chemical Engineering,Chuzhou University;School of Chemistry and Environment Science,Shaanxi University of Technology;

【机构】滁州学院材料与化学工程学院；陕西理工学院化学与环境科学学院；

【摘要】用配体磺基水杨酸,1,10菲罗啉和CuCO3·Cu(OH)2·H2O反应合成了配合物[Cu3(hssal)2(phen)2(H2O)4]·2CH3OH(1)(H3hssal:磺基水杨酸;phen:1,10菲罗啉),用单晶X-射线衍射、元素分析和红外光谱对该配合物进行了表征。研究了1的固体荧光和热稳定性,并用它作为前驱体合成了CuO微晶粒子,用粉末XRD和SEM对合成的CuO进行了表征和形貌研究。更多还原

【Abstract】 A new Cu(Ⅱ) complex[Cu3( hssal)2( phen)2(H2O)4]·2CH3OH(1)( H3hssal: 5-sulfosalicylic acid; phen: 1,10-Phenanthroline) has been synthesized and characterized by single crystal X-ray diffraction,elemental analysis and FT-IR. Thermal stability and luminescent property of 1 are investigated. CuO microcrystal particles were produced by using powder sample of complex 1 as a precursor. The obtained CuO microcrystal is characterized and observed by XRD and SEM analyses.更多还原