Study on the preparation and catalytic activities of iron corrole has become one of the hot topics of porphyrin chemistry. In this paper,the recent progress about catalytic application of iron corrole in organic synthesis has been reviewed,with an emphasis on the oxidation,cyclopropanation and aziridination of olefin,insertion reactions involving N—H,S—H and C —H bonds,[4 + 2] cycloaddition as well as copolymerization of epoxides with carbon dioxide. The problems of iron corroles in catalysis and several di...
【基金】
国家自然科学基金项目(No.21171057,21371059,21261024)资助~~
【更新日期】
2015-06-18
【分类号】
O643.36
【正文快照】
宜春336000;3.Department of Chemistry,Michigan State University,E.Lansing,MI 48824,USA)Contents1 Introduction2 Application of iron-corrole complexes in organicsynthesis2.1 Catalytic oxidation2.2 Catalytic cyclopropanation2.3 Catalytic aziridination2.4 Cata
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