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化学镀银碳纳米管增强银基复合材料的制备和性能

Fabrication and Properties of Silver Composites Reinforced by Silver Coated Carbon Nanotubes

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【作者】 李爱坤谢明张吉明杨有才陈永泰王松刘满门李再久

【Author】 LI Aikun;XIE Ming;ZHANG Jiming;YANG Youcai;CHENG Yongtai;WANG Song;LIU Manmen;LI Zaijiu;State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals;

【机构】 昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室

【摘要】 采用粉末冶金、挤压工艺制备了碳纳米管增强银基(Ag-CNTs(5%,体积比))复合材料丝材,并研究了其导电率、抗拉强度、硬度等物理性能。结果表明,采用混合酸处理可有效改善CNTs的分散性,CNTs表面的银镀层改善了CNTs与Ag基体间的界面结合以及复合材料的致密性,保证了材料的良好加工性能。与纯Ag相比,Ag-CNTs复合材料电阻率提高了30%,而抗拉强度提高了43%,硬度提高了近1倍,说明CNTs起到了较好的增强作用。

【Abstract】 Carbon nanotubes(CNTs) reinforced Ag(Ag-CNTs(5% vol)) composite wire was fabricated by powder metallurgy and extrusion process. Then electrical conductivity, tensile strength, and hardness of the wires were studied. The results indicate that the CNTs could be effectively dispersed after the treatment of mixed acid. The interfacial bonding between Ag matrix and CNTs as well as the compactness of the Ag-CNTs composite was improved by the Ag coating on the CNTs, thus processability of the composite can be ensured. Compared with pure Ag, the Ag-CNTs composite presented an increase in electrical resistivity, tensile strength and hardness by 30%, 43% and nearly 100%, respectively, indicating the good reinforcement effect of CNTs.

【关键词】 复合材料碳纳米管制备性能
【Key words】 composite materialsnanotubessilverpreparationperformance
【基金】 NSFC-云南联合基金(u1302272);云南省科技厅重大项目(KKSB201451004);国家重点实验室开放课题(SKL-SPM-201522)
  • 【分类号】TB333
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