The traditional surfactant can not replace the important role of fluorinated surfactant in some special areas with their unique property.It is systematically to set up a complete set of 19F NMR,1H NMR,13 C NMR spectrums of NMR spectra atlas.The spectra atlas contains more than 100 organic fluorine-containing compounds,and spectrums were collected from experimental results or references.The changing regularity of chemical shifts and coupling constants of various organic fluoride 19F NMR was studied systemati...