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1-乙氨基-2-三氯甲基-咪唑啉的制备及其缓蚀性能
Synthesis and Inhibition Efficiency of 2-(2-trichloromethyl-4,5-dihydro-imidazol-1-yl)-Ethylamine
【摘要】 合成了新型的含氯咪唑啉化合物(CIM),以1H-NMR和FTIR确定其结构。采用静态失重法、动电位极化曲线、电化学阻抗等方法研究了CIM在0.5mol/L盐酸溶液中对碳钢的腐蚀抑制作用。结果表明,CIM的缓蚀率随其浓度增大而增大,且在高温时保持高效的缓蚀性能。CIM在碳钢表面的吸附行为符合Langmuir吸附等温式,属于混合型吸附。
【Abstract】 A novel imidazoline compound,2-(2-trichloromethyl-4,5-dihydro-imidazol-1-yl)-ethylamine(CIM)was synthesized in laboratory.The structure of CIM was identified by 1H-NMR and FTIR. Weight-loss method,potentiodynamic polarization,electrochemical impedance spectroscopy(EIS)techniques and scanning electron microscopy(SEM)were used to investigate the corrosion behavior of mild steel in 0.5mol/L HCl solution with or without CIM. The results showed that the inhibition efficiency of CIM increased with increasing inhibitor concentration and kept effective at high temperatures.The imidazoline compound is a mixed-type inhibitor whose adsorption behavior onto mild steel surface can be well expressed by Langmuir isotherm equation.
【Key words】 chlorine; imidazoline; inhibitor; carbon steel; high temperature;
- 【文献出处】 腐蚀与防护 ,Corrosion & Protection , 编辑部邮箱 ,2015年02期
- 【分类号】TG174.42
- 【被引频次】5
- 【下载频次】151