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聚乙烯醇-魔芋葡甘聚糖/凹凸棒石复合材料的制备与性能

Preparation and Properties of Polyvinyl Alcohol-konjac Glucmannan /Attapulgite Composites

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【作者】 胡盛周红艳杨眉田大听史伯安张升晖

【Author】 Hu Sheng;Zhou Hongyan;Yang Mei;Tian Dating;Shi Boan;Zhang Shenghui;Key Laboratory of Biologic Resources Protection and Utilization of Hubei Province, Hubei University for Nationalities;School of Chemical and Environment Engineering, Hubei University for Nationalities;State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology;Engineering Research Center of Nano-Geo materials of Ministry of Education, China University of Geosciences;

【机构】 湖北民族学院生物资源保护与利用湖北省重点实验室湖北民族学院化学与环境工程学院武汉理工大学材料复合新技术国家重点实验室中国地质大学教育部纳米矿物材料及应用工程研究中心

【摘要】 采用溶液共混法制备了聚乙烯醇-魔芋葡甘聚糖/凹凸棒石复合材料。探讨了聚乙烯醇用量(相对于魔芋葡甘聚糖质量分数,下同)、交联剂戊二醛用量和凹凸棒石用量对聚乙烯醇-魔芋葡甘聚糖/凹凸棒石复合材料力学性能的影响。力学性能测试结果表明,当聚乙烯醇用量为80%、交联剂戊二醛用量为3%、凹凸棒石用量为1%时,聚乙烯醇-魔芋葡甘聚糖/凹凸棒石复合材料的力学性能最好。FT-IR和SEM测试结果表明,复合材料中聚乙烯醇、魔芋葡甘聚糖和凹凸棒石之间存在强烈的相互作用和良好的相容性。

【Abstract】 The polyvinyl alcohol(PVA)-konjac glucmannan(KGM) composites were prepared by blending method. The attapulgite(AT) were dispersed into polyvinyl alcohol-konjac glucmannan matrix to get polyvinyl alcohol-konjac glucmannan/attapulgite composites through blending method with different compositions. Effects of amount of polyvinyl alcohol(compare to the mass of KGM), glutaraldehyde and attapulgite on the properties of polyvinyl alcohol-konjac glucmannan/attapulgite composites were investigated.The mechanical properties show that when the dosage of polyvinyl alcohol, glutaraldehyde and attapulgite were 80%, 3% and 1%, respectively(compare to the mass of KGM), the mechanical properties of the polyvinyl alcohol-konjac glucmannan/attapulgite composites were the best. The composites were characterized by fourier transform infrared spectra(FTIR) and scanning electron microscopy(SEM). The results indicate that the mechanical properties of composites is improved due to the strong interaction and compatibility between konjac glucmannan, polyvinyl alcohol and attapulgite.

【基金】 湖北省教育厅科学技术研究计划青年人才项目(Q20141905);湖北省高校应用化学战略性新兴产业人才培养计划项目(鄂教高(2012)13号);国家自然科学基金地区科学基金(51263009)
  • 【文献出处】 非金属矿 ,Non-Metallic Mines , 编辑部邮箱 ,2015年01期
  • 【分类号】TB332
  • 【被引频次】2
  • 【下载频次】211
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