Monodisperse SPS/ZnO/ZnS hybrid hollow microspheres were synthesized by deposition of ZnO shells on SPS microsphere templates followed by apartial sulfuration process.SPS/ZnO/ZnS hybrid hollow microspheres based nanofilms were fabricated by oil-water assembly method.Then the as-prepared hollow microspheres and nanofilms were annealed in Ar atomosphere to obtain uniform C/ZnO/ZnS hollow microspheres and densely packed C/ZnO/ZnS nanofilms.TEM,SEM,XRD,EDS,HRTEM were employed to characterize the morphology,comp...