节点文献
平衡分布与最概然分布
Equilibrium Distribution and the Most Probable Distribution
【摘要】 以二项分布为例,阐述了平衡分布与最概然分布间的关系。通过子数很多时,二项分布可以变为正态分布以及它的相对涨落与子数的平方根成反比的统计力学原理,阐明了热力学系统的平衡分布可用其最概然分布来代表。
【Abstract】 Taking binomial distribution as an illustration,we elaborated the relationship between equilibrium distribution and the most probable distribution. According to the statistical mechanics,the binomial distribution approximates to the normal distribution when the number is large enough,and the relative fluctuation is inversely proportional to the square root of the number,we illustrated that the equilibrium distribution of a thermodynamic system could be described by the most probable distribution.
【关键词】 平衡分布;
最概然分布;
热力学系统的相对涨落;
【Key words】 Equilibrium distribution; Most probable distribution; Relative fluctuation of thermodynamic system;
【Key words】 Equilibrium distribution; Most probable distribution; Relative fluctuation of thermodynamic system;
【基金】 教育部教育质量工程建设项目(No.YJ0136104);国家精品资源共享课建设项目(No.YJ0125206)
- 【文献出处】 大学化学 ,University Chemistry , 编辑部邮箱 ,2015年06期
- 【分类号】O642.4-4;G642
- 【下载频次】209