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流化床燃煤固硫渣基生态透水砖的制备及性能

Preparation and Performance of Ecological Water-Permeable Bricks Using Desulfurization Slags of Fluidized Bed Coal Combustion

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【作者】 罗绍华郭克石吕方沈惠良牟文宁王志远齐西伟

【Author】 Luo Shaohua;Guo Keshi;Lü Fang;Shen Huiliang;Mou Wenning;Wang Zhiyuan;Qi Xiwei;School of Resources and Materials, Northeastern University at Qinhuangdao Branch;School Materials of and Metallurgy, Northeastern University;Qinhuangdao Laboratory of Resources Cleaner Conversion and Efficient Utilization;Hebei Provincial Laboratory of Dielectric and Electrolyte Functional Materials;

【机构】 东北大学秦皇岛分校资源与材料学院东北大学材料与冶金学院秦皇岛市资源清洁转化与高效利用重点实验室河北省电介质与电解质功能材料重点实验室

【摘要】 以流化床燃煤固硫渣为骨料,水泥为胶凝剂,添加一定量的碱激发剂制备透水砖。设计正交试验研究了固硫渣骨料级配、水泥和碱激发剂用量及成型压力对透水砖性能的影响,优化透水砖的配方和工艺参数。利用X射线衍(XRD)射仪和扫描电镜(SEM)对固硫渣及碱激发水化产物的微观结构进行了分析。结果表明,当10目、20目、60目固硫渣骨料级配为1:1:1,水泥用量35%(质量分数),碱激发剂添加量4%(质量分数),在1.5 MPa压力下成型、室温养护7 d制备出的成品,抗压强度达32 MPa,透水系数为1.3×10-2 cm/s,满足JC/T945-2005《透水砖》相关要求,为固硫渣的综合利用提供了一条新途径。

【Abstract】 The ecological permeable brick was prepared using desulfurization slags as aggregate, cement as gelling agent and alkali activators. A group of orthogonal test was arranged and carried out to study the effect of the mass ratio of slag with different particle size of 10 mesh, 20 mesh and 60 mesh, the content of cement, curing time and molding pressure on performance of permeable brick. The formulation and manufacturing process of permeable brick were optimized. The microstructures of permeable brick and hydras were analyzed by XRD ans SEM. The results show the generated bricks with 32 MPa compressive strength and 0.013 cm/s permeability coefficient could satisfy the JC/T945-2005 standard using the aggregate grading 1:1:1, 35 wt% of cement ratio, 4 wt% of alkali activators and under 1.5 MPa molding pressure and curing at room temperature for 7 d. It has provided a new route for the comprehensive utilization of desulfurization slag.

【基金】 国家自然科学基金资助项目(51374056,51404055);河北省高校百名优秀创新人才支持计划(BR2-127);河北省自然基金-钢铁联合基金(E2013501135);教育部新世纪优秀人才项目(NCET-10-0304);中央高校基本科研业务费(N100123003,N120523001);2013年度陇原青年创新人才扶持计划;河北省高等学校科学技术研究项目(QN2014325);秦皇岛市科技支撑计划项目(201402B005)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2015年S1期
  • 【分类号】TU522.1
  • 【被引频次】6
  • 【下载频次】205
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