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Hydrolysis preparation of the compact TiO2 layer using metastable TiCl4 isopropanol/water solution for inorganic–organic hybrid heterojunction perovskite solar cells

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【作者】 代晓艳史成武张艳茹吴妮

【Author】 Dai Xiaoyan;Shi Chengwu;Zhang Yanru;Wu Ni;School of Chemistry and Chemical Engineering,Hefei University of Technology;Key Laboratory of Novel Thin Film Solar Cells,Chinese Academy of Sciences;

【机构】 School of Chemistry and Chemical Engineering,Hefei University of TechnologyKey Laboratory of Novel Thin Film Solar Cells,Chinese Academy of Sciences

【摘要】 A hydrolysis process was applied to prepare the compact Ti O2 layer using the fresh metastable Ti Cl4isopropanol/water solution as the precursor solution for the preparation of the inorganic–organic hybrid heterojunction perovskite solar cells. The optimal compact Ti O2 layer prepared from the aqueous solution of 2 mol/L Ti Cl4 diluted in isopropanol at 1 : 3 by volume as precursor solution was uniform and with a film thickness of 126 nm.The corresponding perovskite solar cell gave a photovoltaic conversion efficiency of 10.61%.

【Abstract】 A hydrolysis process was applied to prepare the compact Ti O2 layer using the fresh metastable Ti Cl4isopropanol/water solution as the precursor solution for the preparation of the inorganic–organic hybrid heterojunction perovskite solar cells. The optimal compact Ti O2 layer prepared from the aqueous solution of 2 mol/L Ti Cl4 diluted in isopropanol at 1 : 3 by volume as precursor solution was uniform and with a film thickness of 126 nm.The corresponding perovskite solar cell gave a photovoltaic conversion efficiency of 10.61%.

【基金】 Project supported by the National Natural Science Foundation of China(Nos.51472071,51272061,51072043);the National Basic Research Program of China(No.2011CBA00700)
  • 【文献出处】 Journal of Semiconductors ,半导体学报(英文版) , 编辑部邮箱 ,2015年07期
  • 【分类号】TM914.4
  • 【被引频次】3
  • 【下载频次】50
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