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臭氧-生物活性炭联用工艺对腐殖酸去除的影响因素研究

Influencing Factors of Ozone-Biological Activated Carbon Combination Process on Humic Acid Removal

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【作者】 袁君陆纳新高乃云戎文磊周圣东孙子为

【Author】 Yuan Jun;Lu Naxin;Gao Naiyun;Rong Wenlei;Zhou Shengdong;Sun Ziwei;Wuxi City Water Co., Ltd.;State Key Laboratory of Pollution Control and Resource Reuse, Tongji University;

【机构】 无锡市自来水总公司同济大学污染控制与资源化研究国家重点实验室

【摘要】 该文首先研究了臭氧-生物活性炭联用工艺对氯消毒副产物的前体物——腐殖酸的去除效果,并对影响臭氧-生物活性炭去除腐殖酸效果的因素进行了试验研究,具体研究了腐殖酸原液和臭氧-生物活性炭出水分子量分布;初始浓度对臭氧-生物活性炭活性炭联用工艺去除腐殖酸的影响;Mn2+离子、p H值、混凝和沉淀对臭氧-生物活性炭工艺去除腐殖酸的影响。研究结果表明,当腐殖酸初始浓度升高时,臭氧-生物活性炭对腐殖酸的去除率较好;当腐殖酸溶液中存在锰离子时,臭氧-生物活性炭对腐殖酸的去除率升高,并且随锰离子浓度的升高,对腐殖酸的去除率也逐渐升高;p H值的升高、混凝和沉淀都有利于臭氧-生物活性炭对腐殖酸的去除。

【Abstract】 Paper studied the ozone- biological activated carbon(O3-BAC) combination process removal humic acid, precursors of chlorine disinfection byproducts. O3-BAC for humic acid removal effect and influence factors was studied. Molecular weight distribution in the of humic acid liquid and O3-BAC effluent also studied. The effect of initial concentration of humic acid on removal efficiency ozone activated carbon combination process.The effect of Mn2+ions, p H, coagulation and sedimentation process on humic acids were removed by O3-BAC combination process. The results showed that when the initial concentration of humic acid concentration in the water is gradually increased, the removal efficiency of humic acid by O3-BAC is better; When humic acid solution in the presence of manganese ions, the removal efficiency of O3-BAC for humic acid increased, and increased with the concentration of manganese ions, removal of humic acid gradually increased; elevated p H values, coagulation and sedimentation are conducive to O3-BAC for humic acid removal.

【基金】 国家科技重大专项资助(No.2012ZX07403-001;2008ZX07421-002);高等学校博士点基金(No.20120072110050);国家自然科学基金资助项目(No.51178321)
  • 【文献出处】 净水技术 ,Water Purification Technology , 编辑部邮箱 ,2014年S2期
  • 【分类号】TU991.2
  • 【被引频次】12
  • 【下载频次】380
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