Transient competition between photocatalysis and carrier recombination in TiO₂ nanotube film loaded with Au nanoparticles

【摘要】 Highly ordered TiO2 nanotube array(TNA) films are fabricated by using an anodic oxidation method. Au nanoparticles(NPs) films are decorated onto the top of TNA films with the aid of ion-sputtering and thermal annealing. An enhanced photocatalytic activity under ultraviolet C(UVC, 266 nm) light irradiation is obtained compared with that of the pristine TNA, which is shown by the steady-state photoluminescence(PL) spectra. Furthermore, a distinct blue shift in the nanosecond time-resolved transient photoluminescence(NTRT-PL) spectra is observed. Such a phenomenon could be well explained by considering the competition between the surface photocatalytic process and the recombination of the photo-generated carriers. The enhanced UV photocatalytic activities of the Au–TNA composite are evaluated through photo-degradation of methyl orange(MO) in an aqueous solution with ultraviolet–visible absorption spectrometry. Our current work may provide a simple strategy to synthesize defect-related composite photocatalytic devices.更多还原

【Abstract】 Highly ordered TiO2 nanotube array(TNA) films are fabricated by using an anodic oxidation method. Au nanoparticles(NPs) films are decorated onto the top of TNA films with the aid of ion-sputtering and thermal annealing. An enhanced photocatalytic activity under ultraviolet C(UVC, 266 nm) light irradiation is obtained compared with that of the pristine TNA, which is shown by the steady-state photoluminescence(PL) spectra. Furthermore, a distinct blue shift in the nanosecond time-resolved transient photoluminescence(NTRT-PL) spectra is observed. Such a phenomenon could be well explained by considering the competition between the surface photocatalytic process and the recombination of the photo-generated carriers. The enhanced UV photocatalytic activities of the Au–TNA composite are evaluated through photo-degradation of methyl orange(MO) in an aqueous solution with ultraviolet–visible absorption spectrometry. Our current work may provide a simple strategy to synthesize defect-related composite photocatalytic devices.更多还原