【摘要】 采用水热法合成了以叠氮钠和邻菲罗啉为配体的一维链状Cu(Ⅱ)配合物,并通过元素分析、红外光谱、X射线单晶衍射和变温磁化率等技术对配合物进行了表征.该配合物属于三斜晶系,P1空间群,a=1.036 4(2),b=1.199 3(2),c=1.548 1(3)nm,α=87.70(3)°,β=84.58(3)°,γ=79.38(3)°,Z=1,V=1.882 3(7)nm3,d=1.735 mg/m3,F(000)=900.对该配合物的磁学性质进行了讨论.更多还原

【Abstract】 A novel one- dimensional Cu(Ⅱ) complex has been synthesized with sodium azide and phenanthroline as ligands by hydrothermal method and characterized by IR spectroscopy,elemental analyses,X- ray crystallography and magnetic susceptibility in this paper. The single crystal of this complex belongs to the triclinic space group P1 with a = 1. 036 4(2),b = 1. 199 3(2),c = 1. 548 1(3) nm,α = 87. 70(3) °,β = 84. 58(3) °, γ = 79. 38(3) °,Z = 1,V = 1. 882 3(7) nm3,d = 1. 735 mg/m3,F(000) = 900. Magnetic properties of this complex has been discussed.更多还原